2,6,10-Tris(dianisylaminium)-3,7,11- tris(hexyloxy)triphenylene: a robust quartet molecule at room temperature

Organic Letters
Eiji Fukuzaki, Hiroyuki Nishide

Abstract

[reaction: see text] A new triradical molecule, 2,6,10-tris(dianisylaminium)-3,7,11-tris(hexyloxy)triphenylene 1(3+), was synthesized by oxidative trimerization, palladium-catalyzed amination, and subsequent oxidation. It was chemically stable with a half-life > 1 month and displayed the magnetic parameter of S = 3/2 even at room temperature.

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Jan 19, 2006·Journal of the American Chemical Society·Eiji Fukuzaki, Hiroyuki Nishide

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Citations

Mar 10, 2007·Physical Chemistry Chemical Physics : PCCP·M A PimentaR Saito
Sep 14, 2013·Chemical Society Reviews·Piotr BujakAdam Pron
Dec 10, 2019·Chemistry : a European Journal·Atsuki NagataKeiji Okada
Jun 25, 2009·Organic Letters·Jun YinJishan Wu
Aug 30, 2011·Journal of the American Chemical Society·Raffaele R PerrottaDaniel E Falvey
Jun 15, 2014·The Journal of Physical Chemistry. B·Vincent MaurelIrena Kulszewicz-Bajer
Mar 16, 2011·Journal of the American Chemical Society·Andrzej RajcaSuchada Rajca

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