6-(4-Methoxybenzylamino)purin-3-ium chloride

Acta Crystallographica. Section C, Crystal Structure Communications
Zdenek TrávnícekKarel Dolezal

Abstract

The title compound, C13H14N5O+.Cl-, belongs to the group of aromatic cytokinins. These compounds affect a variety of important physiological processes in plants and animals as well as in bacteria, including cell division, differentiation and senescence. The structure consists of a 6-(4-methoxybenzylamino)purinium cation and a Cl- anion. The cation moiety exists as the N3-protonated N7 tautomer. The cation contains nearly planar benzene and purine ring systems, with a dihedral angle of 77.46 (5) degrees. The crystal structure is stabilized by N(amino)-H...N(purine) hydrogen bonds connecting two adjacent molecules, thus forming centrosymmetric dimers.

Citations

Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Zdeněk TrávníčekKamila Stěpánková
May 5, 2011·Acta Crystallographica. Section C, Crystal Structure Communications·Duraisamy Tamilselvi, P Thomas Muthiah

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