9-Borabicyclo[3.3.1]nonane: a metal-free catalyst for the hydroboration of carbodiimides

Chemical Communications : Chem Comm
Alberto RamosDaniel García-Vivó

Abstract

The commercial 9-borabicyclo[3.3.1]nonane dimer is used as the first example of a metal-free catalyst for the monohydroboration of carbodiimides with pinacol borane. Stoichiometric reactions, kinetic studies, and DFT calculations have allowed us to propose a plausible mechanism involving a heterocyclic amidinate intermediate with a three center-two electron B-H-B bond.

References

Sep 3, 2010·Journal of the American Chemical Society·Meghan A Dureen, Douglas W Stephan
Oct 5, 2013·Chemical Society Reviews·Alastair J J Lennox, Guy C Lloyd-Jones
Mar 15, 2014·Chemical Society Reviews·Carlos Alonso-MorenoAntonio Otero
Jan 23, 2015·Journal of the American Chemical Society·Matthew P Mower, Donna G Blackmond
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Apr 14, 2016·Chemistry : a European Journal·Catherine WeetmanMary F Mahon
Nov 2, 2016·Chemical Communications : Chem Comm·Debabrata MukherjeeJun Okuda
Apr 28, 2017·Inorganic Chemistry·Mathew D AnkerMary F Mahon
Feb 22, 2018·Chemistry : a European Journal·Heng LiuMoris S Eisen
Apr 21, 2018·Chemical Communications : Chem Comm·Alberto RamosDaniel García-Vivó

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Citations

Jul 11, 2019·Chemistry : a European Journal·Qiumiao ShenHerbert W Roesky
Jan 7, 2022·Inorganic Chemistry·Abdusalom A SuleymanovKay Severin

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Methods Mentioned

BETA
X-ray
NMR

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