A benzimidazole-based N-heterocyclic carbene derived from 1,10-phenanthroline

Organic Letters
Costa MetallinosMary E A Heska

Abstract

[reaction: see text] A catalytically active palladium-complexed tetracyclic N-heterocyclic carbene (NHC) was prepared in three steps from commercially available 1,10-phenanthroline by using a reduction-cyclization-deprotonation sequence. The new carbene framework is a prototype for the development of a series of chiral N-heterocyclic carbenes.

References

Mar 28, 2002·Journal of the American Chemical Society·Kian L TanJonathan A Ellman
Feb 5, 2004·Journal of the American Chemical Society·Jianrong Zhou, Gregory C Fu

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Citations

May 7, 2005·Organic Letters·Niloufar HadeiMichael G Organ
Jan 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Eun Yeong HwangBun Yeoul Lee
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Sarim DastgirMalcolm L H Green
Feb 1, 2006·Angewandte Chemie·F Ekkehardt Hahn
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Anthony J Arduengo, Luigi I Iconaru
Jun 22, 2010·Journal of the American Chemical Society·Andrew G TennysonChristopher W Bielawski
Mar 14, 2009·Chemical Reviews·Daniela TapuChristopher Roe
Nov 10, 2009·The Journal of Organic Chemistry·Keiichi HiranoFrank Glorius

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