A Bis(Diphosphanyl N-Heterocyclic Carbene) Gold Complex: A Synthon for Luminescent Rigid AuAg2 Arrays and Au5 and Cu6 Double Arrays

Angewandte Chemie
Pengfei AiPierre Braunstein

Abstract

A mononuclear bis(NHC)/Au(I) (NHC=N-heterocyclic carbene) cationic complex with a rigid bis(phosphane)-functionalized NHC ligand (PC(NHC)P) was used to construct linear Au3 and Ag2 Au arrays, a Au5 cluster with two intersecting crosslike Au3 arrays, and an unprecedented Cu6 complex with two parallel Cu3 arrays. The impact of metallophilic interactions on photoluminescence was studied experimentally.

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Citations

Feb 13, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Pengfei AiPierre Braunstein
Jun 16, 2016·Journal of the American Chemical Society·Jiaxiang ChuGuy Bertrand
Jul 7, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Guillermo Moreno-AlcántarHugo Torrens
May 2, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Taotao LuZi-Ling Xue
Oct 7, 2016·Chemical Communications : Chem Comm·M El Sayed MoussaC Lescop
Jan 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Katharine R SampfordPaul D Newman
Jul 25, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sihan ZhangJoji Ohshita
Dec 11, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Guillermo Moreno-AlcántarHugo Torrens
Jan 26, 2020·Chemistry : a European Journal·Kieren J Evans, Stephen M Mansell
Jan 15, 2021·Chemistry, an Asian Journal·Moulali VaddamanuGanesan Prabusankar
Apr 30, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Aleksandra V PaderinaElena V Grachova
Jun 4, 2021·Chemical Reviews·Pierre Braunstein, Andreas A Danopoulos
Mar 8, 2019·Chemical Reviews·Andreas A DanopoulosPierre Braunstein
Jun 20, 2020·Inorganic Chemistry·Guillermo Moreno-AlcántarHugo Torrens
Sep 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Gianmarco TrevisanAndrea Biffis

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