A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides

Journal of the American Chemical Society
Ryan E CowleyPatrick L Holland

Abstract

This communication reports the first examples of transition metal complexes containing an RNNNNNNR 2- ligand. Addition of 1-azidoadamantane to the diiron(I) synthon LRFeNNFeL R (L R = HC[C(R)N(2,6- iPr 2C 6H 3)] 2; R = methyl, tert-butyl) leads to the diiron complexes L RFe(mu-eta2:eta2-AdN6Ad)FeLR, which are surprisingly thermally stable. Magnetic, Mössbauer, and crystallographic data are consistent with pairs of high-spin iron(II) ions antiferromagnetically coupled through a dianionic AdN6Ad 2- bridge.

References

May 31, 2002·Acta Crystallographica. Section B, Structural Science·Frank H Allen
Jan 29, 2005·Organic & Biomolecular Chemistry·Christopher M FitchettPeter J Steel
Jan 19, 2006·Journal of the American Chemical Society·Jeremy M SmithPatrick L Holland
Sep 23, 2006·Angewandte Chemie·Nathan A EckertPatrick L Holland
Nov 9, 2006·Proceedings of the National Academy of Sciences of the United States of America·Michael P HendrichJonas C Peters

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Citations

Jul 24, 2008·Accounts of Chemical Research·Patrick L Holland
Jul 18, 2012·Inorganic Chemistry·Ryan E Cowley, Patrick L Holland
Oct 16, 2013·Inorganic Chemistry·James A BellowStanislav Groysman
Mar 19, 2009·Chemical Communications : Chem Comm·Ryan E CowleyPatrick L Holland
Aug 9, 2015·Journal of Molecular Modeling·Xiuxiu ZhaoSiping Pang
Jan 28, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Tetsuro KizakiSeiji Ogo
Aug 6, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Chi ChenPatrick L Holland
Aug 12, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·S GondzikS Schulz
Jun 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Pokpong RungthanaphatsophonJustin R Walensky
May 3, 2018·Chemistry : a European Journal·Jiliang ZhouDouglas W Stephan
Mar 19, 2009·Angewandte Chemie·Simon J BonyhadyAndreas Stasch
Jul 3, 2019·Chemical Communications : Chem Comm·Amanda GrassStanislav Groysman
Oct 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Mathew D AnkerMartyn P Coles
Nov 21, 2013·Chemical Communications : Chem Comm·S GondzikG Jansen
Mar 11, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Andreas Stasch, Cameron Jones
Aug 12, 2014·Chemical Communications : Chem Comm·Richard A LewisPatrick L Holland
Nov 15, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Jie ZhangXigeng Zhou
Jun 17, 2020·Chemical Reviews·Owen T O'Sullivan, Michael J Zdilla
Apr 29, 2009·Inorganic Chemistry·Ryan E CowleyPatrick L Holland
Aug 19, 2010·Journal of the American Chemical Society·Yu-Chuan LiSi-Ping Pang
Sep 25, 2019·Journal of the American Chemical Society·Yunjung BaekTheodore A Betley
Feb 22, 2014·Inorganic Chemistry·Thomas R DuganPatrick L Holland
Nov 28, 2012·Journal of the American Chemical Society·Thomas R DuganPatrick L Holland
Mar 8, 2019·Organic Letters·Xiaopeng ZhaoWei Yu
Nov 11, 2019·Organometallics·K Cory MacLeodPatrick L Holland
Nov 30, 2021·Chemical Communications : Chem Comm·Bin LiStephan Schulz

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