A case study of energy transfer mechanism from uranium to europium in ZnAl₃O₄ spinel host by photoluminescence spectroscopy

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
Mithlesh Kumar, M Mohapatra

Abstract

Zinc aluminate (ZAO), a member of spinel class of inorganic compounds has been of much interest of late due to its wide range of use in catalysis, optical, electronic and ceramic industries. When doped with several lanthanides, this material has proved to be a potential host matrix for phosphors. As lanthanides suffer from poor (direct) excitation and emission cross sections, the use of a co-dopant ion can help to circumvent this and extract better emission from a lanthanide doped ZAO system. In this connection, energy transfer mechanism from uranium to europium in the ZAO host was investigated by photoluminescence spectroscopic technique. It was seen that uranium gets stabilized in the hexavalent state as UO6(6-) (octahedral uranate) where as the lanthanide ion, Eu is stabilized in its trivalent state in the ZAO host. In the co-doped system, an efficient energy transfer pathway from the uranate to europium ion was observed. Based upon emission and life time data a suitable mechanism was proposed for the energy transfer (quenching) process. It was proposed that after excitation by photons, the uranate ions transfer their energy to nearby (5)D1 level of Eu(3+) ions which non-radiatively de-excites to the corresponding lower leve...Continue Reading

References

Dec 18, 2013·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·B S RavikumarB M Nagabhushana

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