A chemical redox reaction to generate rock salt-type materials: the case of Na3 V2 O5

Dalton Transactions : an International Journal of Inorganic Chemistry
E AdamczykV Pralong

Abstract

Chemical redox reactions are extremely efficient to prepare fully reduced or oxidized phases that are formed during the topotactic insertion/extraction of alkaline ions. Herein, we report these reactions and discuss the possibility to generate new ordered or disordered rock salt-type structures depending on the structure of the mother phase. We have shown that a disordered rock salt-type structure is formed when the transition element is located at the tetrahedral site, as exemplified by the formation of Na3V2O5upon chemical reduction of V2O5.

References

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Dec 15, 2010·Nature Materials·R BerthelotC Delmas
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Nov 26, 2015·Nature Materials·M FreireV Pralong

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Citations

Jun 20, 2018·Materials·Evan AdamczykValerie Pralong

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Methods Mentioned

BETA
X-ray

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