A Chromium Hydroxide/MIL-101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose

Angewandte Chemie
Qiang GuoMichael Tsapatsis

Abstract

A metal-organic framework (MOF)-based catalyst, chromium hydroxide/MIL-101(Cr), was prepared by a one-pot synthesis method. The combination of chromium hydroxide particles on and within Lewis acidic MIL-101 accomplishes highly selective conversion of glucose to fructose in the presence of ethanol, matching the performance of optimized Sn-containing Lewis acidic zeolites. Differently from zeolites, NMR spectroscopy studies with isotopically labeled molecules demonstrate that isomerization of glucose to fructose on this catalyst, proceeds predominantly via a proton transfer mechanism.

References

Apr 23, 2009·Chemical Society Reviews·Liqing MaWenbin Lin
Mar 24, 2010·Proceedings of the National Academy of Sciences of the United States of America·Manuel MolinerMark E Davis
Apr 3, 2010·Chemical Reviews·A CormaF X Llabrés i Xamena
Oct 22, 2010·Angewandte Chemie·Yuriy Román-LeshkovMark E Davis
Oct 8, 2011·Chemical Reviews·Jian-Rong LiHong-Cai Zhou
Jan 28, 2012·Chemical Reviews·Hong-Cai ZhouOmar M Yaghi
Sep 20, 2012·Chemical Society Reviews·Trevor A MakalHong-Cai Zhou
Mar 20, 2013·Journal of the American Chemical Society·Shunmugavel SaravanamuruganAnders Riisager
Jul 24, 2013·Journal of the American Chemical Society·Frederik VermoorteleDirk E De Vos
May 30, 2014·Chemical Society Reviews·Jiewei LiuCheng-Yong Su
Aug 1, 2014·Chemistry, an Asian Journal·George AkiyamaSusumu Kitagawa
Aug 27, 2014·Journal of the American Chemical Society·Juncong JiangWalter G Klemperer
Mar 17, 2015·Nature Materials·Joseph E MondlochOmar K Farha
May 12, 2015·Chemical Society Reviews·Adeel H ChughtaiFrancis Verpoort
Jul 4, 2015·Angewandte Chemie·Jennifer D LewisYuriy Román-Leshkov
Jul 15, 2015·Chemical Society Reviews·N RangnekarM Tsapatsis
Feb 6, 2016·Journal of the American Chemical Society·Camille D MalonzoAndreas Stein
Mar 25, 2017·Chemical Society Reviews·S M J RoggeJ Gascon
May 26, 2017·Chemical Reviews·Li ZhuLin-Bing Sun
Aug 26, 2017·Journal of the American Chemical Society·Kairat SabyrovGabor A Somorjai

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Citations

Nov 28, 2019·Chemical Communications : Chem Comm·Qiang GuoMichael Tsapatsis
May 13, 2020·Chemical Society Reviews·Ruiqi FangHermenegildo Garcia
Apr 25, 2020·Chemistry : a European Journal·Lifei LianYu-Fei Song
Jun 20, 2020·Angewandte Chemie·Jingwei HouLianzhou Wang
Sep 6, 2019·Chemical Communications : Chem Comm·David L BurnettRichard I Walton
Apr 22, 2021·Journal of Agricultural and Food Chemistry·Zhaohui GuoYingxiong Wang
Jun 2, 2021·Langmuir : the ACS Journal of Surfaces and Colloids·Krittish RoyDipankar Mandal

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