A combined quantum-chemical and matrix-isolation study on molecular manganese fluorides

Dalton Transactions : an International Journal of Inorganic Chemistry
Felix BrosiSebastian Riedel

Abstract

Molecular manganese fluorides were studied using quantum-chemical calculations at DFT and CCSD(T) levels and experimentally by matrix-isolation techniques. They were prepared by co-deposition of IR-laser ablated elemental manganese or manganese trifluoride with F2 in an excess of Ne, Ar, or N2 or with neat F2 at 5-12 K. New IR bands in the Mn-F stretching region are detected and assigned to matrix-isolated molecular MnFx (x = 1-3).

References

Feb 24, 2001·Inorganic Chemistry·S Nunziante CesaroL N Sidorov
Sep 9, 2004·Chemical Reviews·Sumitra MukhopadhyayWilliam H Armstrong
Jun 16, 2007·Inorganic Chemistry·Sebastian RiedelMartin Kaupp
Mar 4, 1994·Science·T VogtJ K Cockcroft
Jul 3, 2010·Inorganic Chemistry·Sebastian RiedelLester Andrews
Oct 26, 2012·Angewandte Chemie·Tobias SchlöderSebastian Riedel
May 17, 2014·Inorganic Chemistry·Tobias SchlöderSebastian Riedel
Jun 4, 2015·Angewandte Chemie·Thomas Vent-SchmidtSebastian Riedel
Oct 3, 2015·Chemistry : a European Journal·Felix BrosiSebastian Riedel

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