A comprehensive investigation on the thermal and toxic hazards of large format lithium-ion batteries with LiFePO4 cathode

Journal of Hazardous Materials
Yang PengYong Ni

Abstract

Toxic gases released from lithium-ion battery (LIB) fires pose a very large threat to human health, yet they are poorly studied, and the knowledge of LIB fire toxicity is limited. In this paper, the thermal and toxic hazards resulting from the thermally-induced failure of a 68 Ah pouch LIB are systematically investigated by means of the Fourier transform infrared spectroscopy (FTIR) and 1/2 ISO full scale test room. The LIBs with higher state of charge (SOC) are found to have greater fire risks in terms of their burning behavior, normalized heat release rate, and fire radiation, as well as the concentration of toxic gases. Specifically, the thermal hazards are evaluated by combining the effects of convective and radiative heat. The major toxic gases detected from the online analysis are CO, HF, SO2, NO2, NO and HCl. Furthermore, Fractional Effective Dose (FED) and Fractional Effective Concentration (FEC) models are used to quantitatively assess the overall gas toxicity. Results show that the effects of irritant gases are much more significant than those of asphyxiant gases. HF and SO2 have much greater toxicity than the other fire gases. The maximum FEC value is approaching the critical threshold in such fire scenarios.

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Fundamental and Applied Toxicology : Official Journal of the Society of Toxicology
B C LevinS E Harris
Voenno-medit︠s︡inskiĭ zhurnal
V A BasharinP G Tolkach
Science
J B TerrillC F Reinhardt
© 2021 Meta ULC. All rights reserved