A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2

Chemical Communications : Chem Comm
Alexander KrollViktoria H Gessner

Abstract

The isolation, structural characterization and coordination chemistry of a di(amino)-substituted carbodiphosphorane (CDP) are reported. Compared to the analogue, dianionic bis(iminophosphoryl)methandiides, the CDP is a stronger C-, but much weaker N-donor which led to the isolation of solely C-coordinated metal complexes amongst an unusual monomeric trigonal-planar L·ZnCl2 complex.

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Citations

Dec 23, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yinwu LiRobert Langer
Oct 30, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Lili ZhaoGernot Frenking
Apr 30, 2021·Chemistry : a European Journal·Wei SuQing Ye

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Methods Mentioned

BETA
NMR

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