A general approach to non-fullerene electron acceptors based on the corannulene motif

Chemical Communications : Chem Comm
Viktor BarátMihaiela C Stuparu

Abstract

Here, we show that oxidation of exo-cyclic sulfur atoms enhances the molecular reduction potential of non-planar polycyclic aromatic hydrocarbons and allows for a systematic bridging of the electron affinity gap between corannulene, a fragment of fullerene C60, and the prevalent fullerene-based electron acceptor phenyl-C61-butyric acid methyl ester (PCBM).

References

Dec 26, 2001·Journal of the American Chemical Society·S MizyedL T Scott
Oct 29, 2005·Angewandte Chemie·Elizabeta Amir, Shlomo Rozen
Dec 15, 2006·Chemical Reviews·Vikki M Tsefrikas, Lawrence T Scott
Apr 12, 2012·Angewandte Chemie·Igor V KuvychkoOlga V Boltalina
Oct 28, 2015·Accounts of Chemical Research·Christian B NielsenIain McCulloch
May 15, 2018·Chemical Communications : Chem Comm·Eleni Nestoros, Mihaiela C Stuparu
Jun 7, 2018·Accounts of Chemical Research·Alexander V ZabulaMarina A Petrukhina

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Citations

Sep 9, 2020·Chemical Communications : Chem Comm·Bening Tirta MuhammadWei Lin Leong
Aug 28, 2020·Chemistry : a European Journal·Johannes BayerThomas Huhn
Oct 22, 2020·Chemistry, an Asian Journal·Viktor Barát, Mihaiela C Stuparu
Jun 12, 2021·Accounts of Chemical Research·Mihaiela C Stuparu
Mar 11, 2020·The Journal of Organic Chemistry·Sergio FerreroCeledonio M Álvarez

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Methods Mentioned

BETA
column chromatography
cyclic voltammetry
X-ray

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