A giant M2 L3 metallo-organic helicate based on phthalocyanines as a host for electroactive molecules

Chemical Communications : Chem Comm
Ettore FazioT Torres

Abstract

An unprecedented Fe2Pc3metallo-organic helicate has been assembled using a bidentate phthalocyanine (Pc) ligand, 2-formylpyridine and Fe(OTf)2. This giant helicate has proved itself as a host for large redox-active guests such as fullerene and naphthalenediimide derivatives. Photoactivated electronic interactions between components occur in the host-guest complex.

References

Feb 19, 2002·Chemical Reviews·Claude PiguetGérard Hopfgartner
Sep 14, 2010·Chemical Communications : Chem Comm·M Victoria Martínez-DíazTomás Torres
Oct 7, 2011·Chemical Society Reviews·Francis D'Souza, Osamu Ito
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Jul 17, 2014·Chemical Society Reviews·Salvatore ZarraJonathan R Nitschke
Sep 3, 2014·Organic Letters·Ettore FazioTomás Torres
Apr 21, 2016·Angewandte Chemie·Felix J RizzutoJonathan R Nitschke
Aug 9, 2016·Journal of the American Chemical Society·Tanya K RonsonJonathan R Nitschke
Sep 1, 2016·Journal of the American Chemical Society·Javier Fernández-ArizaTomás Torres

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Citations

May 22, 2018·Chemical Communications : Chem Comm·Hae-Geun JeonKyu-Sung Jeong
Feb 19, 2019·Chemistry : a European Journal·Aaron D W KennedyJonathon E Beves
Jun 4, 2020·Chemistry : a European Journal·Erica GiraldiKay Severin
Nov 3, 2020·Chemistry, an Asian Journal·Masayuki MorieTakeharu Haino
May 24, 2021·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Mingshui ZhangGuangjiu Zhao
Jul 27, 2021·Frontiers in Chemistry·Lynn S LisboaJames D Crowley
Dec 27, 2018·Inorganic Chemistry·María J RomeroAna M González-Noya

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Methods Mentioned

BETA
column chromatography
X-ray
fluorescence titrations
fluorescence titration

Software Mentioned

Scigress
ReactLab TM EQUILIBRIA

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