A highly concentrated catholyte based on a solvate ionic liquid for rechargeable flow batteries

Advanced Materials
Kensuke TakechiYoko Hase

Abstract

A redox-active supercooled liquid is obtained by forming a "solvate ionic liquid" from a mixture of a stabilized organic radical and a specific Li salt and stabilizing the mixture further below their melting points. As a catholyte, the addition of an appropriate amount of water helps to enhance the electrochemical advantage while maintaining its supercooled nature and the liquid shows a high energy density of 200 W h L(-1) with reversible charge/discharge.

References

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Citations

Nov 26, 2015·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Feng Pan, Qing Wang
Apr 20, 2017·Physical Chemistry Chemical Physics : PCCP·Samuel W ColesVladislav B Ivaništšev
Jul 15, 2016·Physical Chemistry Chemical Physics : PCCP·Jeffrey J BlackLeigh Aldous
Aug 24, 2016·Chemical Communications : Chem Comm·Yoko HaseKensuke Takechi
Aug 18, 2018·Advanced Materials·Ruiting Yan, Qing Wang
Sep 9, 2017·Advanced Materials·Akihiro ShimizuJun-Ichi Yoshida
Jan 11, 2017·Angewandte Chemie·Jan WinsbergUlrich S Schubert
Oct 19, 2017·Chemical Society Reviews·Yu DingGuihua Yu
Mar 3, 2021·Angewandte Chemie·Jiahan SongYongzhu Fu
Apr 25, 2018·ACS Applied Materials & Interfaces·Koki KawaseSeimei Shiratori
May 11, 2019·Journal of the American Chemical Society·Lily A RobertsonY Z
Aug 24, 2021·ACS Applied Materials & Interfaces·Xuefeng ZhangHongning Chen
Jul 17, 2020·Accounts of Chemical Research·Changkun ZhangGuihua Yu

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