A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

Chemical Communications : Chem Comm
Jing ZhangJunhua Luo

Abstract

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2- polyanionic zigzag chains, which shows above-room-temperature switching of quadratic nonlinear optical (NLO) properties induced by the unique order-disorder conformational changes of the organic cation.

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Citations

Jul 4, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Gang ChenWei-Qiang Liao
Dec 22, 2020·Chemical Communications : Chem Comm·Yu-Hua LiuWei-Qiang Liao

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Methods Mentioned

BETA
X-ray
differential scanning calorimetry

Software Mentioned

CAmbridge Sequential Total Energy Package ( CASTEP )

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