A luminescent supramolecular Cu2 I2 (NH3 )2 -sandwiched Cu3 (pyrazolate)3 adduct as a temperature sensor

Dalton Transactions : an International Journal of Inorganic Chemistry
Shun-Ze ZhanDan Li

Abstract

A highly luminescent supramolecular Cu2I2(NH3)2-sandwiched Cu3(pyrazolate)3 adduct was reported as a temperature sensor. The adduct is stabilized by the synergy of intermolecular Cu3I (π acidbase), CuCu and NH interactions, to form a Cu8I2 cluster. The emission intensity exhibits a temperature-dependent effect in the solid state with a sensitivity of -0.685% K-1. DFT and TDDFT calculations revealed that the luminescence originates from the triplet state of Cu8I2 cluster-centered charge transfer (3CC).

References

Nov 10, 2004·Acta Crystallographica. Section B, Structural Science·Joshua J McKinnonAnthony S Mitchell
Jan 6, 2005·Journal of the American Chemical Society·Akihiro KishimuraTakuzo Aida
Dec 22, 2006·Angewandte Chemie·Jie-Peng ZhangSusumu Kitagawa
Feb 9, 2007·Angewandte Chemie·H V Rasika Dias, Chammi S Palehepitiya Gamage
Jan 16, 2008·Journal of the American Chemical Society·Sammer M TekarliMohammad A Omary
Jan 26, 2008·Chemical Communications : Chem Comm·Joshua J McKinnonMark A Spackman
Sep 14, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng-Cheng DuanRaphael G Raptis
Nov 12, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Giovanni F CaramoriGernot Frenking
Jan 20, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Yunlong WuYao-Yu Wang
Feb 26, 2015·Chemical Communications : Chem Comm·Yuanjing CuiGuodong Qian
Jul 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Yan NingYao-Yu Wang
Nov 2, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Charlie E Kivi, Datong Song

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Citations

Nov 10, 2018·Chemical Communications : Chem Comm·Aleksei A TitovElena S Shubina
Jan 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuan TianThomas C W Mak
Jan 3, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jing-Huo ChenPeng Cheng
Jan 19, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Shun-Ze ZhanDan Li
Oct 23, 2019·The Journal of Organic Chemistry·Kazumasa TanimotoHiroki Iida

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