A mesoporous metal-organic framework based on a shape-persistent macrocycle

Chemical Communications : Chem Comm
Teng-Hao ChenOgnjen Š Miljanić

Abstract

A mesoporous Zn-based metal-organic framework (MOF) was prepared from a shape-persistent phenylene ethynylene macrocycle functionalized with three -COOH groups. The rigid ligand has a ∼9 Å wide central cavity which serves as a predesigned pore. The macrocycles [π···π] stack into pairs, with their carboxylate groups connected via three Zn3O14C6H2 clusters. The resulting MOF has a void volume of 86%.

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Citations

Jan 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Teng-Hao ChenSeth M Cohen
Jan 28, 2016·Journal of the American Chemical Society·Jesús MosqueraJonathan Nitschke
Jul 3, 2015·Organic & Biomolecular Chemistry·Merry K Smith, Ognjen Š Miljanić
Nov 26, 2016·Chemistry : a European Journal·Teng-Hao ChenOgnjen Š Miljanić
Mar 11, 2017·Chemical Communications : Chem Comm·Pei-Zhou LiYanli Zhao
Feb 23, 2021·Angewandte Chemie·Adrian Saura-SanmartinJose Berna
Dec 12, 2018·ACS Applied Materials & Interfaces·Xiaohui XuHexiang Deng
Dec 21, 2016·Journal of the American Chemical Society·Wolfgang BrennerJonathan R Nitschke

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