A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones

Chemical Communications : Chem Comm
Yan-Mei NieJun Yan

Abstract

The as-synthesized (TBA)8H5[Nd(SiW11O39)2] manifested high catalytic activity for cyanosilylation of ketones, and its catalytic activity could be improved further through rational design of the reaction micro-environment beyond the molecular level, and the corresponding mechanism has been systematically studied.

References

Feb 18, 2004·Angewandte Chemie·Zhonghua Peng
Dec 23, 2004·Journal of the American Chemical Society·Guang LiuTianbo Liu
Jul 26, 2005·Chemical Communications : Chem Comm·Wen LiMin Li
Apr 11, 2008·Chemical Communications : Chem Comm·Anna ProustPierre Gouzerh
Feb 5, 2010·Angewandte Chemie·De-Liang LongLeroy Cronin
Jul 12, 2012·Chemical Society Reviews·Anna ProustGuillaume Izzet
Aug 2, 2012·Chemical Society Reviews·Yu-Fei Song, Ryo Tsunashima
May 13, 2015·Chemical Reviews·Sa-Sa Wang, Guo-Yu Yang
Jun 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Haiyan AnJianjun Zhang
Jan 5, 2019·Journal of the American Chemical Society·Peng YangNiveen M Khashab

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