A nanoring-nanosphere molecule, {Mo214V30}: pushing the boundaries of controllable inorganic structural organization at the molecular level

Journal of the American Chemical Society
Bogdan BotarCraig L Hill

Abstract

A controlled, Raman-monitored chemical reduction of a molybdate and vanadate mixture affords a new type of molybdenum-oxide-based cluster showing an unprecedented level of inorganic structural organization. The cluster incorporates two nanosized substructures (a ring and a sphere) in an open clam-like assembly. Multiple methods indicate that the nanoring contains delocalized electrons and the nanosphere contains localized but interacting electrons.

References

Mar 29, 2000·Accounts of Chemical Research·A Müller, C Serain
Mar 3, 2001·Science·T E Mallouk
Apr 12, 2001·Nature·M N Leuenberger, D Loss
Feb 9, 2005·Physical Review Letters·Christian SchröderPaul Kögerler
May 25, 2005·NMR in Biomedicine·Elisenda RodríguezCoral Sanfeliu

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Citations

Oct 28, 2009·Angewandte Chemie·Bogdan BotarPaul Kögerler
Dec 22, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul KögerlerAchim Müller
Jan 26, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Ryosuke KawaharaSayaka Uchida
Sep 15, 2012·Chemistry : a European Journal·Jin ZhangYongge Wei
Sep 21, 2006·Angewandte Chemie·Ranko P Bontchev, May Nyman
Jul 30, 2009·Physical Chemistry Chemical Physics : PCCP·M FittipaldiD Gatteschi
Apr 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Shuang YaoEnbo Wang
Jun 22, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Bogdan BotarPaul Kögerler
Sep 14, 2012·Chemical Society Reviews·Hongjin LvCraig L Hill
Jan 18, 2014·Chemical Communications : Chem Comm·Mariyatra B MahimaidossWolfgang Schmitt
Jun 30, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Melissa L KistlerAchim Müller
Dec 22, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Haralampos N MirasLeroy Cronin
Mar 8, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Keyu CuiJianping Zhang
Jul 23, 2008·Journal of the American Chemical Society·Sayaka Shishido, Tomoji Ozeki
Jul 1, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·Melissa L KistlerTianbo Liu
Mar 11, 2008·Inorganic Chemistry·Xiang-Jian KongLan-Sun Zheng
Aug 22, 2012·Journal of the American Chemical Society·Peng HuangEn-Bo Wang
Sep 5, 2014·Journal of the American Chemical Society·Weimin XuanLeroy Cronin
Jun 27, 2007·Inorganic Chemistry·Nikolaos I KapakoglouThemistoklis A Kabanos

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