A neutral branched platinum-acetylide complex possessing a tetraphenylethylene core: preparation of a luminescent organometallic gelator and its unexpected spectroscopic behaviour during sol-to-gel transition

Chemical Communications : Chem Comm
Yuan-Yuan RenLin Xu

Abstract

A neutral branched platinum-acetylide complex TPA possessing a tetraphenylethylene core was successfully prepared, which was found to form luminescent organometallic gels in ethyl acetate. Stimulated by temperature or F(-), the reversible gel-sol transition was realized. More interestingly, TPA exhibited an unexpected blue shift of the emission during the sol-to-gel transition.

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Citations

Dec 2, 2015·Chemical Communications : Chem Comm·Zheng Xu, Lin Xu
Jul 12, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Zheng XuLin Xu
Oct 21, 2016·Chemistry : a European Journal·Alexander RödleGustavo Fernández
Dec 7, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuan-Yuan RenLin Xu
Jan 24, 2019·Macromolecular Rapid Communications·Yan GeZhenhui Qi
May 7, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Stefano TodiscoPiero Mastrorilli
Apr 22, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Lin Xu, Hai-Bo Yang
Dec 1, 2016·ChemPlusChem·Peng ZhangYun-Bao Jiang

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