A new insert sample approach to paper spray mass spectrometry: a paper substrate with paraffin barriers

The Analyst
T C ColletesB G Vaz

Abstract

The analytical performance for paper spray (PS) using a new insert sample approach based on paper with paraffin barriers (PS-PB) is presented. The paraffin barrier is made using a simple, fast and cheap method based on the stamping of paraffin onto a paper surface. Typical operation conditions of paper spray such as the solvent volume applied on the paper surface, and the paper substrate type are evaluated. A paper substrate with paraffin barriers shows better performance on analysis of a range of typical analytes when compared to the conventional PS-MS using normal paper (PS-NP) and PS-MS using paper with two rounded corners (PS-RC). PS-PB was applied to detect sugars and their inhibitors in sugarcane bagasse liquors from a second generation ethanol process. Moreover, the PS-PB proved to be excellent, showing results for the quantification of glucose in hydrolysis liquors with excellent linearity (R(2) = 0.99), limits of detection (2.77 mmol L(-1)) and quantification (9.27 mmol L(-1)). The results are better than for PS-NP and PS-RC. The PS-PB was also excellent in performance when compared with the HPLC-UV method for glucose quantification on hydrolysis of liquor samples.

References

Apr 15, 2005·Analytical Chemistry·Robert B CodyH Dupont Durst
Feb 18, 2010·Analytical Chemistry·Jiangjiang LiuZheng Ouyang
Jun 4, 2010·Analytical and Bioanalytical Chemistry·Rosana M AlbericiMarcos N Eberlin
Jul 20, 2010·Annual Review of Analytical Chemistry·Min-Zong HuangJentaie Shiea
Feb 22, 2012·International Journal of Mass Spectrometry·Qian YangZheng Ouyang
Jun 19, 2013·The Analyst·Yuan SuZheng Ouyang
Aug 3, 2013·Analytical and Bioanalytical Chemistry·Attilio NaccaratoAntonio Tagarelli
Mar 14, 2014·Rapid Communications in Mass Spectrometry : RCM·Robert B Cody, A John Dane
Mar 20, 2014·Angewandte Chemie·Rahul NarayananThalappil Pradeep
Nov 20, 2014·Analytical Chemistry·Gert I J SalentijnElisabeth Verpoorte
May 30, 2015·Analytical Chemistry·Michael WleklinskiR Graham Cooks
Nov 2, 2015·Analytical and Bioanalytical Chemistry·Yue RenZheng Ouyang

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Citations

Dec 3, 2017·Journal of the American Society for Mass Spectrometry·Ludmyla S TavaresAndréa R Chaves
Sep 7, 2019·Mass Spectrometry Reviews·Benjamin S FreyAbraham K Badu-Tawiah
Oct 2, 2020·Analytical Methods : Advancing Methods and Applications·Miriam Beneito-CambraAntonio Molina-Díaz
Jun 1, 2018·Journal of Analytical Methods in Chemistry·Federica BianchiMaria Careri
May 9, 2016·Micromachines·Lori Shayne Alamo BusaManabu Tokeshi
Aug 23, 2019·Journal of Mass Spectrometry : JMS·Gregory W Vandergrift, Chris G Gill
Sep 16, 2020·Analytical Methods : Advancing Methods and Applications·M C Díaz-LiñánA I López-Lorente
Jul 28, 2020·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Sangkaew PrapapornDungchai Wijitar
Jun 6, 2021·Environmental Science and Pollution Research International·Ricardo Alves BernardoAndréa Rodrigues Chaves
Jun 27, 2021·Scientific Reports·Preeyarad CharoensumranThanit Praneenararat
Oct 5, 2019·Langmuir : the ACS Journal of Surfaces and Colloids·Deidre E DamonAbraham K Badu-Tawiah
Oct 14, 2017·Analytical Chemistry·Max HechtKarin Kipper
Feb 23, 2019·Analytical Chemistry·Clara L FeiderLivia S Eberlin
Nov 20, 2018·Analytical Chemistry·G Ij SalentijnE Verpoorte
Sep 16, 2020·Journal of the American Society for Mass Spectrometry·Marcella Ferreira RodriguesBoniek Gontijo Vaz
Feb 8, 2020·Journal of the American Society for Mass Spectrometry·William L FatiganteChristopher C Mulligan

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