A new series of Co, Ni, Zn, and Cd metal-organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties

Dalton Transactions : an International Journal of Inorganic Chemistry
Jin-Zhong GuAlexander M Kirillov

Abstract

This study reports the hydrothermal synthesis of a novel series of twelve coordination compounds, namely, {[Cd(μ-Hnbtc)(H2O)4]·H2O}n (1), [Zn2(μ-Hnbtc)2(phen)2]·2H2O (2), [Zn(Hnbtc)(phen)2(H2O)]·4.5H2O (3), [Ni(Hnbtc)(phen)2(H2O)]·6H2O (4), [Zn2(μ-Hnbtc)2(2,2'-bipy)2]·2H2O (5), [Cd3(μ5-nbtc)(μ6-nbtc)(2,2'-bipy)2(H2O)]n (6), {[Zn3(μ3-nbtc)2(phen)3(H2O)2]·4H2O} (7), [Co(H2O)6][Co2(nbtc)2(μ-4,4'-bipy)(4,4'-bipy)2(H2O)6]·8H2O (8), {[Ni3(μ4-nbtc)2(μ-4,4'-bipy)2.5(μ-H2O)(H2O)3]·4H2O}n (9), {[Cd2(μ4-nbtc)(μ-OH)(2,2'-bipy)2]·H2O}n (10), [Cd2(μ4-nbtc)(μ-OH)(phen)2(H2O)]n (11), and {[Zn2(μ5-nbtc)(μ3-OH)(μ-4,4'-bipy)]·4,4'-bipy·H2O}n (12), which are derived from 3'-nitro-biphenyl-2,4,4'-tricarboxylic acid (H3nbtc) as a virtually unexplored building block. These compounds were generated in aqueous medium from the corresponding metal(ii) chlorides as a metal source, H3nbtc as a principal building block, NaOH as a base, and simple N,N-donor aromatic ligands as crystallization mediators (i.e., 1,10-phenanthroline, phen; 2,2'-bipyridine, 2,2'-bipy; or 4,4'-bipyridine, 4,4'-bipy). All products 1-12 were completely characterized in the solid state by IR spectroscopy, elemental and thermogravimetric (TGA) analyses, powder (PXRD) and single-crysta...Continue Reading

References

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Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·Anthony L Spek
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Aug 3, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Jin-Zhong GuAlexander M Kirillov
Nov 2, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Sebastian F M SchmidtAnnie K Powell
Dec 5, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Emilio BeginesAgustín Galindo
Dec 15, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Serhii I VasylevskyiKatharina M Fromm

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Citations

May 22, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Na ZhaoAlexander M Kirillov
May 19, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jin-Zhong GuAlexander M Kirillov
Sep 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Brajesh KumarSubrata Das

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