A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks

Chemistry : a European Journal
Sergey A AdoninVladimir P Fedin

Abstract

In the presence of different cations, reactions of [SbBr6 ]3- and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix }n- polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9 kcal mol-1 . Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.

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Citations

Jan 14, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Anastasia V ChupinaMaxim N Sokolov
Dec 12, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Anastasiya A EliseevaVadim Yu Kukushkin
Dec 24, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Markus Ströbele, Hans-Jürgen Meyer
Jul 17, 2020·Chemistry : a European Journal·Yana V ProkudinaAlexey Y Timoshkin

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