A P-H Functionalized Al/P Frustrated Lewis Pair: Substrate Activation and Selective Hydrogen Transfer

Angewandte Chemie
Lukas KewelohWerner Uhl

Abstract

Hydroalumination of an alkynylphosphine gave an unprecedented P-H functionalized frustrated Lewis pair (FLP). The reactive P-H group does not influence the typical FLP properties, but the activation of substrates follows a new reaction pattern involving hydrogen transfer to yield unusual compounds with phosphaurea, iminophosphine, or phosphanyltriazene structural motifs.

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Citations

Dec 8, 2016·Chemistry : a European Journal·Lisa-Maria ElmerGerhard Erker
Jul 22, 2016·Chemical Communications : Chem Comm·Leif A KörteNorbert W Mitzel
Oct 12, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Linda E EijsinkEdwin Otten
Aug 23, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhongbao JianGerhard Erker
Aug 30, 2018·Angewandte Chemie·Jian YangAlexandre Martinez
Sep 27, 2018·Chemistry : a European Journal·Jorge Juan Cabrera-Trujillo, Israel Fernández
Dec 20, 2018·Chemical Communications : Chem Comm·Jorge Juan Cabrera-Trujillo, Israel Fernández
Sep 10, 2019·Chemistry : a European Journal·Devin H A BoomJ Chris Slootweg
Sep 10, 2019·Chemistry : a European Journal·Xiong SunCongqing Zhu
Dec 10, 2019·Angewandte Chemie·Michael A K WeinhartManfred Scheer
Jan 18, 2020·Chemistry : a European Journal·Xiong SunCongqing Zhu
Jul 26, 2017·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Damian PleschkaWerner Uhl
Sep 8, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Evi R M HabrakenJ Chris Slootweg
Nov 25, 2020·Chemistry : a European Journal·Jorge Juan Cabrera-Trujillo, Israel Fernández
Oct 2, 2021·Angewandte Chemie·Jun LiGerhard Erker

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