A Practical Aryliodine(I/III) Catalysis for the Vicinal Diamination of Styrenes

ChemSusChem
Eric CotsKilian Muñiz

Abstract

2,6-Disubstituted iodoarenes bearing amide-functionalized side arms are reported as new structures in redox-active iodine(I/III) catalysis. In combination with bis-sulfonimides as nitrogen sources and 3-chloroperbenzoic acid (mCPBA) as benign terminal oxidant they catalyze the vicinal diamination of styrenes. The obtained reactivity and selectivity outperform other iodoarene catalyst candidates. This protocol provides a sustainable alternative to previous related protocols for diamination that are based on stoichiometric iodine(III) reagents.

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Citations

Feb 6, 2020·Chemistry, an Asian Journal·Ankita BalPrasenjit Mal
Jan 13, 2021·Organic Letters·Heng-Hui LiPei-Qiang Huang
Apr 27, 2021·Organic Letters·Ming DongXiaofeng Tong
Jul 21, 2021·Organic & Biomolecular Chemistry·Yusuke KobayashiYoshiji Takemoto
Jun 17, 2020·The Journal of Organic Chemistry·Lucien CaspersBoris Johannes Nachtsheim

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