A primary reference method for the characterization of Cd, Cr, Cu, Ni, Pb and Zn in a candidate certified reference seawater material: TEA/Mg(OH)2 assisted ID3MS by triple quadrupole ICP-MS/MS.

Analytica Chimica Acta
Betül Arı, Sezgin Bakırdere

Abstract

A certified reference seawater material (CRM), UME CRM 1206 which was sampled from the Marmara Sea (40 31,423 N; 027 11, 333 E) with 27 psu of salinity is about to be released by Inorganic Analysis Laboratory of TÜBİTAK National Metrology Institute (UME). This paper represents the characterization measurements of Cd, Cr, Cu, Ni, Pb and Zn in this CRM. The use of a reference method by a single laboratory is one of the options for the characterization of a candidate CRM according to ISO 17034 [39]. This approach is used throughout this study with an introduction of a primary reference method. For this purpose, combination of triethylamine assisted Mg(OH)2 co-precipitation and triple isotope dilution mass spectrometry (TEA/Mg(OH)2-ID3MS) were developed and validated. This optimized co-precipitation protocol provided the recovery of target analytes within the range of 72%-92% which was the main advantage of TEA/Mg(OH)2 method especially for Cd, Ni, Cu and Zn compared to NH4OH assisted co-precipitation. Analytical performance of TEA/Mg(OH)2-ID3MS were investigated under the optimum conditions. The results for matrix certified reference material were found to be not significantly different from the certified values based on the compa...Continue Reading

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.