A redox-active diborane platform performs C(sp3 )-H activation and nucleophilic substitution reactions

Chemical Science
Thomas KaeseMatthias Wagner

Abstract

Organoboranes are among the most versatile and widely used reagents in synthetic chemistry. A significant further expansion of their application spectrum would be achievable if boron-containing reactive intermediates capable of inserting into C-H bonds or performing nucleophilic substitution reactions were readily available. However, current progress in the field is still hampered by a lack of universal design concepts and mechanistic understanding. Herein we report that the doubly arylene-bridged diborane(6) 1H2 and its B 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 000000000000000000...Continue Reading

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Citations

Jun 21, 2018·Chemistry : a European Journal·Yoshiaki ShojiTakanori Fukushima
May 9, 2019·Organic & Biomolecular Chemistry·Sven KirschnerMatthias Wagner
Jul 3, 2019·Angewandte Chemie·Seiji AkiyamaMakoto Yamashita
Jul 12, 2019·Chemical Communications : Chem Comm·Anne-Frédérique PécharmanMary F Mahon
Dec 14, 2019·Angewandte Chemie·Jannik GilmerMatthias Wagner
Oct 24, 2019·Angewandte Chemie·Aishabibi KassymbekGeorgii I Nikonov
Feb 15, 2020·Angewandte Chemie·Timo TrageserMatthias Wagner
Mar 4, 2021·Chemical Reviews·Xiaojun SuCaleb D Martin
Apr 16, 2020·Chem·Xin MuAlexander M Spokoyny
Mar 30, 2021·Angewandte Chemie·Kelsie E WentzRobert J Gilliard
Jun 25, 2021·Chemical Science·Jiang HeTodd B Marder
Jun 24, 2021·Angewandte Chemie·Hendrik BudyMatthias Wagner
Jul 2, 2021·Angewandte Chemie·Tobias HeitkemperChristian P Sindlinger
Mar 16, 2019·Journal of the American Chemical Society·Esther von GrotthussMatthias Wagner
Jun 26, 2020·Inorganic Chemistry·Sabrina KhooCheuk-Wai So
Jan 15, 2019·Chemical Reviews·Marc-André LégaréHolger Braunschweig
Sep 15, 2021·Chemical Communications : Chem Comm·Shreenibasa SaKrishnan Venkatasubbaiah
Dec 10, 2021·Chemical Communications : Chem Comm·Hendrik BudyMatthias Wagner

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Methods Mentioned

BETA
X-ray
NMR

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