A Series of Bimetallic Ammonium AlNa Formates

Chemistry : a European Journal
Yao YuSong Gao

Abstract

A series of AlNa bimetallic ammonium metal formate frameworks (AlNa AMFFs) have been prepared by employing various ammoniums from NH4+ to large linear polyammoniums. The series consists of six perovskites of (412 ⋅63 ) topology for mono-ammoniums, two chiral (49 ⋅66 ) frameworks incorporating polyethylene ammoniums, two niccolites with (412 ⋅63 )(49 ⋅66 ) topology containing diammoniums, and two layered compounds made of 2D (4,4) AlNa formate sheets intercalated by small diammoniums. The first ten compounds present the structural hierarchy of (412 ⋅63 )m (49 ⋅66 )n framework topologies for (m, n)=(1, 0), (0, 1), and (1, 1), respectively, in parallel to the homometallic AMFFs for divalent metals. The symmetry lowering, asymmetric formate bridges, and different hydrogen-bonding strengths appeared in the bimetallic structures owing to the different charge and size of Al3+ and Na+ seemingly inhibits the occurrence of phase transitions for more than half the AlNa AMFFs within the series, and the bimetallic members undergoing phase transitions show different transition behaviors and dielectric properties compared with the homometallic analogs. Anisotropic/negative/zero thermal expansions of the materials could be rationally attribute...Continue Reading

References

Jul 28, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Zheming WangMohamedally Kurmoo
Oct 6, 2007·Science·Anthony K Cheetham, C N R Rao
Dec 21, 2007·Angewandte Chemie·Anthony E PhillipsCameron J Kepert
Feb 5, 2009·Acta Crystallographica. Section C, Crystal Structure Communications·Agnieszka Plutecka, Urszula Rychlewska
Dec 18, 2009·Journal of the American Chemical Society·Anthony E PhillipsCameron J Kepert
Mar 30, 2010·Advanced Materials·Zheming WangHayao Kobayashi
Jun 30, 2010·Journal of the American Chemical Society·Guan-Cheng XuSong Gao
Dec 3, 2010·Nature Chemistry·Satoshi HorikeSusumu Kitagawa
Mar 18, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhiming DuanSong Gao
May 10, 2011·Chemical Society Reviews·Joel S Miller, Dante Gatteschi
May 10, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Mengyuan LiMohamedally Kurmoo
Aug 30, 2011·Journal of the American Chemical Society·Guan-Cheng XuSong Gao
Sep 24, 2011·Chemical Reviews·Wen Zhang, Ren-Gen Xiong
Oct 21, 2011·Angewandte Chemie·Da-Wei FuTakayoshi Nakamura
Jan 28, 2012·Chemical Reviews·Hong-Cai ZhouOmar M Yaghi
Feb 4, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Jin-Chong TanAnthony K Cheetham
May 24, 2012·Physical Chemistry Chemical Physics : PCCP·B Pato-DoldánM A Señarís-Rodríguez
Jul 5, 2012·Journal of the American Chemical Society·Wei LiAnthony K Cheetham
Mar 9, 2013·Chemical Society Reviews·Andrew B Cairns, Andrew L Goodwin
Mar 30, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Dipankar SahaTayur N Guru Row
Apr 16, 2013·Journal of the American Chemical Society·Ilne GroblerLeonard J Barbour
Apr 24, 2013·Journal of the American Chemical Society·Ines E CollingsAndrew L Goodwin
Aug 31, 2013·Science·Hiroyasu FurukawaOmar M Yaghi
Apr 9, 2014·Accounts of Chemical Research·Thomas D Bennett, Anthony K Cheetham
Jul 19, 2014·Journal of the American Chemical Society·Aurélie U OrtizFrançois-Xavier Coudert
Oct 14, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Mirosław MączkaAdam Pikul
Mar 17, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Mirosław MączkaJ Hanuza
Jun 30, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Aneta CiupaMaciej Ptak
Sep 10, 2015·Chemical Communications : Chem Comm·Gregor KieslichAnthony K Cheetham
Oct 20, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Ines E CollingsAndrew L Goodwin

❮ Previous
Next ❯

Citations

Jul 4, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Shu LiuSong Gao
Dec 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Maciej PtakWaldeci Paraguassu
Aug 25, 2020·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Dan G DumitrescuArie van der Lee
Oct 31, 2019·Journal of the American Chemical Society·Hanna L B BoströmAndrew L Goodwin

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.