A series of dithiocarbamates for americium, curium, and californium

Dalton Transactions : an International Journal of Inorganic Chemistry
Samantha K CaryPing Yang

Abstract

Characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)3(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm-S (mean of 2.86 ± 0.04 Å) and Cf-S (mean of 2.84 ± 0.04 Å) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)3(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions.

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Citations

Feb 9, 2019·Chemical Communications : Chem Comm·Ingrid Lehman-AndinoKonstantinos Kavallieratos
Jun 14, 2019·Angewandte Chemie·Conrad A P GoodwinPing Yang
Mar 26, 2019·Chemistry : a European Journal·Frankie D WhiteThomas E Albrecht-Schmitt
Sep 20, 2019·Angewandte Chemie·J August RidenourChristopher L Cahill
Jul 17, 2020·Nature·Joseph M SperlingThomas E Albrecht-Schönzart
Apr 20, 2021·Inorganic Chemistry·Nathan P BessenJenifer C Shafer
Jun 26, 2021·Chemical Science·Zachary R JonesDavid H Woen
Oct 9, 2020·Inorganic Chemistry·Roger KloditzJuliane März
Dec 21, 2018·Inorganic Chemistry·Alexander T ChemeyThomas E Albrecht-Schmitt
Jul 11, 2020·Inorganic Chemistry·Joseph M SperlingThomas E Albrecht-Schönzart
Dec 4, 2019·Journal of the American Chemical Society·Benjamin W SteinPing Yang
Jul 11, 2019·Inorganic Chemistry·Matthew L MarshThomas E Albrecht-Schmitt
Oct 30, 2020·Inorganic Chemistry·R D M GreerThomas E Albrecht-Schönzart
Sep 28, 2021·Inorganic Chemistry·Shane S GalleySuzanne C Bart
Jan 25, 2022·Chemical Communications : Chem Comm·Joseph M SperlingThomas E Albrecht-Schönzart

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Methods Mentioned

BETA
X-ray
ion exchange chromatography
optical spectroscopy

Software Mentioned

SHAPE8
APEX
SAINT
PLATON
Gaussian
SHELX

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