A Size-Flexible Organometallic Box for the Encapsulation of Fullerenes

Angewandte Chemie
Víctor Martínez-AgramuntEduardo Peris

Abstract

A palladium-cornered molecular square with four pyrene-bis(imidazolylidene) bridging ligands is reported. This metallo-polygon can encapsulate C60 and C70 . The X-ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo-square, showing that it can adjust the shape of its cavity to the size of each fullerene.

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Citations

Oct 18, 2019·Chemical Communications : Chem Comm·Dan PrestonPaul E Kruger
Nov 30, 2019·Chemical Communications : Chem Comm·Víctor Martínez-Agramunt, Eduardo Peris
Jun 16, 2021·Chemical Communications : Chem Comm·Marvin MetzelaarsPaul Kögerler
Jun 15, 2021·Chemical Science·Alex J PlajerJonathan R Nitschke
Aug 14, 2019·Inorganic Chemistry·Víctor Martínez-Agramunt, Eduardo Peris
Jul 10, 2020·Accounts of Chemical Research·Susana IbáñezEduardo Peris
Jul 10, 2020·Journal of the American Chemical Society·Ya-Wen ZhangYing-Feng Han

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