A stereodivergent asymmetric approach to difluorinated aldonic acids

Chemical Communications : Chem Comm
Christophe AudouardClive A Smith

Abstract

A (bromodifluoromethyl)alkyne has been deployed in a stereoselective route to difluorinated aldonic acid analogues, in which a Sharpless asymmetric dihydroxylation reaction and diastereoisomer separation set the stage for phenyl group oxidation.

References

Sep 1, 2000·Carbohydrate Research·K DaxB J Paul
Feb 11, 2004·Organic & Biomolecular Chemistry·Christophe AudouardClive A Smith

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Citations

Jul 8, 2016·The Journal of Organic Chemistry·Satoru Arimitsu, Makoto Nakasone
Dec 22, 2017·Chemistry, an Asian Journal·Zhen-Yu WangXi-Sheng Wang
Feb 20, 2009·Organic & Biomolecular Chemistry·Audrey CaravanoKuldip Singh
Dec 22, 2009·Organic & Biomolecular Chemistry·Timo AnderlKuldip Singh
Aug 2, 2008·Organic Letters·Roxana S Timofte, Bruno Linclau
Jun 11, 2009·Organic Letters·Riccardo SurmontNorbert De Kimpe
Oct 5, 2006·Journal of the American Chemical Society·Gerry A GriffithMark A Vincent

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