A supersalt-type copper(i)-thiolate cluster with applications for mechano/thermochromism and the oxygen evolution reaction

Chemical Communications : Chem Comm
Lanxia HuJian Zhang

Abstract

A new copper(i)-thiolate (Cu-S) cluster with a CsCl unit (1, [Cu12(μ4-SCH3)6(NH3)12][Cu12(μ4-SCH3)6Cl12]) exhibited interesting mechanochromic and thermochromic luminescence properties. Additionally, heteroatom-rich 1 could also be used as an electrocatalyst for the oxygen evolution reaction in alkaline media. The supersalt-type Cu-S cluster for the first time realized mechano/thermochromic and electrocatalytic applications.

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Citations

May 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Jia-Ming LiKun-Huan He
Aug 12, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Sandrine Perruchas

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Methods Mentioned

BETA
X-ray

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