A tetranuclear arylstibonic acid with an adamantane type structure

Dalton Transactions : an International Journal of Inorganic Chemistry
Julian BrünigJens Beckmann

Abstract

Oxidative chlorination of ArSbCl2 (1) with SO2Cl2 provided ArSbCl4 (2), the base hydrolysis of which gave rise to the arylstibonic acid (ArSb)4O6(OH)4 (3) having an adamantane type structure. The intramolecularly coordinating substituent Ar = 6-diphenylphosphinoacenaphth-5-yl- modulates the Lewis acidity of 1-3 and prevents extensive aggregation.

References

Feb 22, 2007·Journal of the American Chemical Society·Viswanathan BaskarRichard E P Winpenny
Dec 3, 2008·Chemical Communications : Chem Comm·Shoaib AliRichard E P Winpenny
Dec 17, 2008·Inorganic Chemistry·Luis F Piedra-GarzaUlrich Kortz
Feb 14, 2009·Chemical Communications : Chem Comm·Christopher J ClarkCody E Wright
Oct 1, 1946·Journal of the American Chemical Society·G O DOAK, H G STEINMAN
Oct 1, 1946·Journal of the American Chemical Society·G O DOAK
Jul 5, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Brian K NicholsonTania Groutso
Sep 8, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Ananda Kumar Jami, Viswanathan Baskar
Oct 2, 2013·Inorganic Chemistry·Jens BeckmannStefan Mebs

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Citations

Mar 18, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·M Santhana Raj PrabhuViswanathan Baskar
Dec 19, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Uppara Ugandhar, Viswanathan Baskar
Feb 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sinas FuranJens Beckmann
Apr 19, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Mengxi YangFrançois P Gabbaï
Jan 3, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Rajesh DekaHarkesh B Singh

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