A theoretical study on the reaction of ozone with aqueous iodide

Physical Chemistry Chemical Physics : PCCP
Óscar GálvezLuis F Pacios

Abstract

Atmospheric iodine chemistry plays a key role in tropospheric ozone catalytic destruction, new particle formation, and as one of the possible sinks of gaseous polar elemental mercury. Moreover, it has been recently proposed that reaction of ozone with iodide on the sea surface could be the major contributor to the chemical loss of atmospheric ozone. However, the mechanism of the reaction between aqueous iodide and ozone is not well known. The aim of this paper is to improve the understanding of such a mechanism. In this paper, an ab initio study of the reaction of aqueous iodide and ozone is presented, evaluating thermodynamic data of the different reactions proposed in previous experimental studies. In addition, the structures, energetics and possible evolution of the key IOOO(-) intermediate are discussed for the first time.

References

Mar 10, 2001·Journal of Photochemistry and Photobiology. B, Biology·L A MartinezE Oliveros
Jun 7, 2002·Nature·Colin D O'DowdThorsten Hoffmann
Dec 11, 2003·Chemical Reviews·Lucy J Carpenter
Aug 12, 2005·Chemical Reviews·Jacopo TomasiRoberto Cammi
Dec 22, 2006·The Journal of Physical Chemistry. B·Jie ChengA J Colussi
Jul 21, 2007·Science·Alfonso Saiz-LopezJohn M C Plane
Aug 24, 2007·The Journal of Physical Chemistry. a·S EnamiA J Colussi
Apr 27, 2010·The Journal of Physical Chemistry. a·Sayaka HayaseAgustín J Colussi
Oct 19, 2010·The Journal of Chemical Physics·Joonghan KimYoon Sup Lee
Oct 29, 2011·Chemical Reviews·Alfonso Saiz-LopezRussell W Saunders
Aug 15, 2013·Physical Chemistry Chemical Physics : PCCP·O GálvezL F Pacios
Aug 31, 2013·Environmental Science & Technology·Elizabeth A Pillar-LittleJose M Rodriguez
May 16, 2015·Journal of the Air & Waste Management Association·Arlene M FioreEric M Leibensperger
Mar 10, 2009·Journal of Chemical Theory and Computation·Patrick NicholsW A de Jong
May 11, 2010·Journal of Chemical Theory and Computation·Luis F Pacios, Oscar Gálvez

❮ Previous
Next ❯

Citations

May 29, 2019·Physical Chemistry Chemical Physics : PCCP·Ricky TeiwesHenrik B Pedersen
Aug 21, 2020·Physical Chemistry Chemical Physics : PCCP·Henrik B PedersenMerete Bilde
Sep 10, 2019·Physical Chemistry Chemical Physics : PCCP·Carolina Moreno, María Teresa Baeza-Romero
Nov 17, 2020·The Journal of Physical Chemistry. a·Stephanie R SchneiderJonathan P D Abbatt

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

© 2022 Meta ULC. All rights reserved