A three-dimensional complex with a one-dimensional cobalt-hydroxyl chain based on planar nonanuclear clusters showing spin-canted antiferromagnetism

Inorganic Chemistry
Bao LiJun Tao

Abstract

A new three-dimensional magnetic network, [Co9(OH)6(C42H24O18P3N3)2(H2O)8] (1), has been successfully prepared by utilizing the flexible hexacarboxylate ligand derived from cyclotriphosphazene, which had been characterized by single-crystal X-ray diffraction and magnetic measurement. This compound consists of one-dimensional (1D) cobalt-hydroxyl chains based on planar nonanuclear clusters, which are located in the b-c plane to form the nearly two-dimensional cobalt layer. Magnetic measurements reveal that 1 shows spin-canted antiferromagnetism with spin-glass behavior. These results suggest that reasonable design and choice of large carboxylate ligand based on a specific scaffold could be effective for the construction of magnetic materials based on a novel 1D magnetic chain.

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Citations

Jul 20, 2016·Chemical Communications : Chem Comm·Ju-Fang HuChang-Wen Hu
Aug 10, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jong Won ShinKil Sik Min
Oct 30, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Lei GengP Shiv Halasyamani
Nov 30, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhao-Xi WangMing-Xing Li
Jan 26, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Aylin Uslu, Serkan Yeşilot

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