A tin-free route to trans-diels-alder motifs by visible light photoredox catalysis

The Journal of Organic Chemistry
Jun Hee Lee, Sun-Il Mho

Abstract

A tin-free trans-Diels-Alder paradigm for the stereoselective synthesis of trans-fused polycyclic systems was developed through the photocatalytic reductive dehalogenation of α-haloketones promoted by visible light. Good to excellent diastereoselectivities were observed in the stereoselective construction of trans-fused octalone derivatives under mild reaction conditions.

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Citations

Sep 14, 2016·Journal of the American Chemical Society·Wenxin ChenGuigen Li
Aug 6, 2015·Organic & Biomolecular Chemistry·Ricardo A AngnesGerald B Hammond
Nov 8, 2016·Chemical Society Reviews·Nathaniel CorriganCyrille Boyer
Nov 28, 2018·Organic Letters·Kyu Dong Kim, Jun Hee Lee

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