A triclinic polymorph of 1,3-thiazolidine-2-thione (2-mercaptothiazoline)

Acta Crystallographica. Section C, Crystal Structure Communications
Rodrigo S CorrêaAntônio C Doriguetto

Abstract

A planar conformation of 1,3-thiazolidine-2-thione (TZDTH), C3H5NS2, was crystallized for the first time. The new triclinic polymorph (P\overline 1) obtained was compared in terms of its intra- and intermolecular geometry with three previous reports of a monoclinic polymorph (P2(1)/n). The packing is based on centrosymmetric dimers of TZDTH, linked by N-H...S hydrogen bonds.

Citations

Jan 1, 2008·Acta Crystallographica. Section E, Structure Reports Online·Rodrigo S CorrêaJulio Duque
Jan 30, 2008·Journal of Pharmaceutical Sciences·Harry G Brittain
Apr 6, 2012·Acta Crystallographica. Section C, Crystal Structure Communications·I M R LandreA C Doriguetto
Sep 2, 2011·Acta Crystallographica. Section C, Crystal Structure Communications·Rodrigo S CorrêaAlzir A Batista
Sep 4, 2010·Acta Crystallographica. Section C, Crystal Structure Communications·I M R LandreA C Doriguetto
Jun 3, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Cornelia VetterDirk Steinborn

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