A zinc(II) metal-organic framework with a novel topology formed from 4,4',4''-nitrilotribenzoate and 4,4'-bipyridine ligands

Acta Crystallographica. Section C, Structural Chemistry
Meng ZhaoYu Peng Tian

Abstract

A metal-organic framework with a novel topology, poly[sesqui(μ2-4,4'-bipyridine)bis(dimethylformamide)bis(μ4-4,4',4''-nitrilotribenzoato)trizinc(II)], [Zn3(C21H12NO6)2(C10H8N2)1.5(C3H7NO)2]n, was obtained by the solvothermal method using 4,4',4''-nitrilotribenzoic acid and 4,4'-bipyridine (bipy). The structure, determined by single-crystal X-ray diffraction analysis, possesses three kinds of crystallographically independent Zn(II) cations, as well as binuclear Zn2(COO)4(bipy)2 paddle-wheel clusters, and can be reduced to a novel topology of a (3,3,6)-connected 3-nodal net, with the Schläfli symbol {5.6(2)}4{5(2).6}4{5(8).8(7)} according to the topological analysis.

References

Apr 28, 2005·Journal of the American Chemical Society·Eun Young LeeMyunghyun Paik Suh
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Jan 28, 2009·Acta Crystallographica. Section D, Biological Crystallography·Anthony L Spek
Oct 12, 2010·Journal of the American Chemical Society·Kyoungmoo KohAdam J Matzger
Mar 19, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Mathias KöberlFritz E Kühn
Jun 22, 2011·Chemical Reviews·Yuanjing CuiBanglin Chen
Nov 17, 2011·Chemical Reviews·Minyoung YoonKimoon Kim
Dec 24, 2011·Chemical Reviews·Myunghyun Paik SuhDae-Woon Lim
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·George M Sheldrick
Jan 9, 2015·Acta Crystallographica. Section C, Structural Chemistry·Anthony L Spek

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Citations

Aug 9, 2019·Journal of Biochemical and Molecular Toxicology·Mediha SüleymanoğluBahri Ülküseven
Jun 6, 2020·Acta Crystallographica. Section C, Structural Chemistry·Yong Jin ZhaoYu Bin Dong
Mar 4, 2017·Acta Crystallographica. Section C, Structural Chemistry·Xue Ru WangYu Bin Dong

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