Ab initio theoretical study of temperature and density dependence of molecular and thermodynamic properties of water in the entire fluid region: autoionization processes

The Journal of Physical Chemistry. B
Norio YoshidaFumio Hirata

Abstract

The temperature and density dependence of the molecular and thermodynamic properties of water is investigated theoretically by means of the ab initio electronic structure theory combined with the reference interaction site model method, so-called RISM-SCF. We consider the autoionization process (H2O + H2O right harpoon over left harpoon H3O+ + OH-) by regarding H2O, H3O+, and OH- as "solute" molecules in an aqueous solution and evaluate molecular geometry, electronic structure, solvation structure, and the ionic product of water (pKw) of these species as functions of thermodynamic conditions. In our previous paper, we calculated these properties by using essentially the same method in a wide range of density values (0.6-1.4 g/cm3). However, the calculation was limited at rather higher density (>0.6 g/cm3) due to the difficulty of convergence, which is inherent to the hypernetted-chain (HNC) closure. The problem is overcome in this study by employing the Kovalenko-Hirata (KH) closure which hybridizes the HNC and the mean-spherical approximation (MSA). Here, we present the results for the thermodynamic range of densities from 0.025 to 1.0 g/cm3 and for temperatures from 300 to 800 K including the supercritical point.

References

Apr 26, 2005·The Journal of Chemical Physics·Takuma YagasakiIwao Ohmine

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Citations

Mar 19, 2014·The Journal of Chemical Physics·Masaru MatsugamiFumio Hirata
Apr 24, 2013·Physical Chemistry Chemical Physics : PCCP·Hirofumi Sato
Sep 2, 2017·Scientific Reports·Eva PerltFrank Weinhold
Dec 31, 2009·The Journal of Physical Chemistry. B·Daisuke YokogawaYoshifumi Kimura
Jul 4, 2009·The Journal of Physical Chemistry. B·Kentaro KidoShigeyoshi Sakaki
Aug 25, 2010·The Journal of Physical Chemistry. B·Viwat VchirawongkwinShigeyoshi Sakaki

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