Achieving a rare breathing behavior in a polycatenated 2D to 3D net through a pillar-ligand extension strategy

Chemistry : a European Journal
Xiaoliang ZhaoDaofeng Sun

Abstract

Through a pillar-ligand extension strategy, a rare breathing behavior in polycatenated 2D→3D nets has been achieved. Three variants exhibit interesting sorption properties that range from non-breathing to breathing behaviors, which is influenced by the angles between the pillars and the single honeycomb layers. The increase in pillar length does not lead to an increase in polycatenation multiplicity, which is controlled by the length of intralayer tripodal carboxylate. It also does not induce obviously expanded interlayer separations but occupies much more the free voids, and as a consequence, a smaller pore volume is obtained. This suggests that in 2D→3D polycatenated bilayer metal-organic frameworks, the porosity is not always enhanced by increasing the length of the interlayer pillars with the intralayer linker remaining unchanged.

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Citations

Nov 12, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Tien-Wen TsengKuang-Lieh Lu
May 13, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Ping WuYao-Yu Wang
Jul 9, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Dana BejanChristoph Janiak
Aug 29, 2014·Chemical Communications : Chem Comm·Hao-Tian ZhangHai-Long Jiang
Jun 12, 2014·Chemical Reviews·Lucia CarlucciVladislav A Blatov

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