Actinide Organometallic Complexes with π-Ligands

Chemistry : a European Journal
Olaf Walter

Abstract

Recent developments and results from the organometallic chemistry of the actinides are reviewed. In the last one and a half years the structural data of about 15 organometallic complexes of transuranium actinides (Np or Pu) have been published, all involving π-ligands in the coordination sphere of the metal ion. On the basis of these data, a comparison of these molecules is presented. Depending on the steric demands of the ligands, effects like the actinide contraction seem to be stronger or weaker in the structural features. This indicates that the interplay between the actinide ion and the π-ligand is rather flexible, enabling the formation of stable bonds over a broad range of actinide ion oxidation states.

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Citations

Aug 15, 2019·Angewandte Chemie·Alexander J MyersJustin R Walensky
Apr 25, 2020·Angewandte Chemie·Holger BraunschweigMuralee Murugesu
Sep 22, 2020·Chemical Communications : Chem Comm·Benjamin L L RéantDavid P Mills
Jan 17, 2021·Chemistry : a European Journal·David P Mills, Peter Evans
May 6, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jingjing LiuDavid P Mills
Jun 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael A BoreenJohn Arnold
Apr 2, 2021·Journal of the American Chemical Society·Jingzhen DuStephen T Liddle
Sep 4, 2021·Journal of the American Chemical Society·Erik RheinfrankWilli Auwärter

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