Active Molybdenum-Based Anode for Dehydrogenative Coupling Reactions

Angewandte Chemie
Sebastian B BeilSiegfried R Waldvogel

Abstract

A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required MoV reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.

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Citations

Apr 1, 2018·Angewandte Chemie·Youai QiuLutz Ackermann
May 29, 2018·Chemical Communications : Chem Comm·Sebastian B BeilSiegfried R Waldvogel
Jun 19, 2018·Chemical Society Reviews·Markus D Kärkäs
Sep 13, 2018·Chemistry : a European Journal·Yongyuan GaoYi Pan
Dec 12, 2018·Chemistry : a European Journal·Peter FranzmannSiegfried R Waldvogel
Jul 26, 2019·Angewandte Chemie·Marek GrzybowskiDaniel T Gryko
Jul 3, 2019·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Xiao-De An, Jian Xiao
Jun 9, 2020·Chemical Communications : Chem Comm·Yong-Zheng YangJin-Heng Li
Apr 28, 2020·Chemistry : a European Journal·Stephan P BlumSiegfried R Waldvogel
Dec 30, 2020·Angewandte Chemie·Stephan P BlumSiegfried R Waldvogel
Jan 12, 2021·Angewandte Chemie·Sebastian B BeilSiegfried R Waldvogel
Jun 15, 2021·Chemical Science·Dennis Pollok, Siegfried R Waldvogel
Jun 20, 2018·Organic Letters·Sebastian B BeilSiegfried R Waldvogel
Jul 3, 2018·Chemical Reviews·Siegfried R WaldvogelChristopher J Kampf
Sep 17, 2019·Organic Letters·Chung-Yen LiChin-Fa Lee
Dec 19, 2019·Accounts of Chemical Research·Johannes L RöcklSiegfried R Waldvogel
Feb 19, 2019·Organic Letters·Alexander LippTill Opatz
Jan 5, 2019·The Journal of Organic Chemistry·Lingling DengJianlin Han

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