Addition of C-H Bonds of Pyridine Derivatives to Alkenes Catalyzed by Zirconium Complexes Bearing Amine-Bridged Bis(phenolato) Ligands

Inorganic Chemistry
Qiu SunYingming Yao

Abstract

Cationic zirconium complexes in situ generated from zirconium dibenzyl complexes bearing amine-bridged bis(phenolato) ligands have been developed to catalyze addition of C(sp2)-H and C(sp3)-H bonds of pyridine derivatives to alkenes. A series of zirconium complexes bearing different ligands have been synthesized, and their activities in catalyzing addition of C(sp3)-H bonds of pyridine derivatives to alkenes have been studied and compared. Both reaction activity and regioselectivity are influenced by electronic and steric properties of ligand backbones. In addition, a cationic zirconium complex has been isolated and structurally characterized to shed some light on reaction mechanism.

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Citations

Aug 22, 2020·Organic & Biomolecular Chemistry·Yan-Long LuoBing-Tao Guan

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