Alkaline earths as main group reagents in molecular catalysis

Chemical Society Reviews
Michael S HillCatherine Weetman

Abstract

The past decade has witnessed some remarkable advances in our appreciation of the structural and reaction chemistry of the heavier alkaline earth (Ae = Mg, Ca, Sr, Ba) elements. Derived from complexes of these metals in their immutable +2 oxidation state, a broad and widely applicable catalytic chemistry has also emerged, driven by considerations of cost and inherent low toxicity. The considerable adjustments incurred to ionic radius and resultant cation charge density also provide reactivity with significant mechanistic and kinetic variability as group 2 is descended. In an attempt to place these advances in the broader context of contemporary main group element chemistry, this review focusses on the developing state of the art in both multiple bond heterofunctionalisation and cross coupling catalysis. We review specific advances in alkene and alkyne hydroamination and hydrophosphination catalysis and related extensions of this reactivity that allow the synthesis of a wide variety of acyclic and heterocyclic small molecules. The use of heavier alkaline earth hydride derivatives as pre-catalysts and intermediates in multiple bond hydrogenation, hydrosilylation and hydroboration is also described along with the emergence of thes...Continue Reading

References

Jun 13, 2002·Chemical Reviews·Gary A Molander, Jan Antoinette C Romero
Mar 4, 2003·Chemical Communications : Chem Comm·Malcolm H ChisholmKhamphee Phomphrai
Dec 4, 2003·Journal of the American Chemical Society·Sukwon HongTobin J Marks
Sep 24, 2004·Accounts of Chemical Research·Sukwon Hong, Tobin J Marks
Oct 13, 2004·Inorganic Chemistry·Malcolm H ChisholmKhamphee Phomphrai
Feb 17, 2005·Journal of the American Chemical Society·Mark R CrimminMichael S Hill
Apr 28, 2005·Journal of the American Chemical Society·Amber M Kawaoka, Tobin J Marks
May 12, 2005·Chemical Reviews·Michael E Jung, Grazia Piizzi
Sep 1, 2005·Journal of the American Chemical Society·Geoffrey H SpikesPhilip P Power
Mar 21, 2006·Angewandte Chemie·Frank BuchSjoerd Harder
Apr 26, 2006·Angewandte Chemie·Sjoerd Harder, Julie Brettar
May 18, 2007·Journal of the American Chemical Society·Xianghua YuTobin J Marks
Oct 3, 2007·Chemistry : a European Journal·Jan Spielmann, Sjoerd Harder
Nov 10, 2007·Science·Shaun P GreenAndreas Stasch
Feb 20, 2008·Angewandte Chemie·Matthias Westerhausen
May 1, 2008·The Journal of Organic Chemistry·Alma Dzudza, Tobin J Marks
May 24, 2008·Inorganic Chemistry·Sankaranarayanapillai SarishJörg Magull
Oct 18, 2008·Angewandte Chemie·Shaun P GreenAndreas Stasch
Oct 29, 2008·Chemical Communications : Chem Comm·Anthony G M BarrettPanayiotis A Procopiou
Mar 27, 2009·Journal of the American Chemical Society·Jan Spielmann, Sjoerd Harder
Mar 31, 2009·Inorganic Chemistry·Anthony G M BarrettPanayiotis A Procopiou
May 1, 2009·Angewandte Chemie·Merle ArrowsmithMary F Mahon
Jun 26, 2009·Journal of the American Chemical Society·Mark R CrimminPanayiotis A Procopiou
Aug 27, 2009·Journal of the American Chemical Society·Anthony G M BarrettPanayiotis A Procopiou
Apr 10, 2010·Chemical Communications : Chem Comm·Michael S HillThomas P Robinson
May 22, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Charles J Weiss, Tobin J Marks
Jun 15, 2010·Chemistry : a European Journal·David J LiptrotDugald J MacDougall
Jun 22, 2010·Chemistry : a European Journal·Jan SpielmannSjoerd Harder
Jul 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Anthony G M BarrettPanayiotis A Procopiou
Sep 11, 2010·Chemical Communications : Chem Comm·Michael S HillThomas P Robinson
Dec 2, 2010·Journal of the American Chemical Society·James F DunneAaron D Sadow
Apr 8, 2011·Angewandte Chemie·Sjoerd HarderHeinz Bandmann
Apr 9, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael S HillMary F Mahon

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Citations

Jul 1, 2016·Journal of the American Chemical Society·Evan N KeyzerDominic S Wright
Sep 30, 2016·Inorganic Chemistry·Stephan M HärlingMatthias Westerhausen
Apr 13, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ashim BaishyaSharanappa Nembenna
Mar 10, 2016·Chemistry : a European Journal·Yann SarazinJean-François Carpentier
Mar 8, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Milan Kr BarmanSharanappa Nembenna
Feb 9, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Milan Kumar BisaiSakya S Sen
Jan 26, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·S SchnitzlerJ Okuda
Jun 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Debabrata MukherjeeJun Okuda
Jul 27, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Benjamin FreitagSjoerd Harder
Feb 17, 2018·Chemistry : a European Journal·Billa PrashanthSanjay Singh
Apr 25, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Ji-Dong LengDavid P Mills
Oct 13, 2017·Chemical Communications : Chem Comm·Diego A Resendiz-LaraIan Manners
Oct 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Sorin-Claudiu RoşcaYann Sarazin
Apr 24, 2018·Angewandte Chemie·Holger ElsenSjoerd Harder
Nov 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·A A TrifonovA A Kissel
Nov 2, 2016·Chemical Communications : Chem Comm·Debabrata MukherjeeJun Okuda
Sep 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Antonio MartínezFernando Carrillo-Hermosilla
Sep 7, 2017·Chemical Communications : Chem Comm·Andrea CauseroSjoerd Harder
May 18, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Anne-Frédérique PécharmanMary F Mahon
Jun 13, 2018·Chemical Communications : Chem Comm·Jürgen PahlSjoerd Harder
Jun 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu ZhangYingming Yao
Jun 27, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Farid M SroorMichel Etienne
Mar 27, 2018·Angewandte Chemie·Debabrata MukherjeeJun Okuda
Aug 7, 2017·Angewandte Chemie·Brant MaitlandSjoerd Harder
Jul 14, 2018·Chemistry : a European Journal·Matthew M D RoyEric Rivard
Sep 8, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Sjoerd Harder, Warren E Piers
Sep 20, 2018·Angewandte Chemie·Heiko BauerSjoerd Harder
Oct 18, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jiaye Jin, Mingfei Zhou
Jan 4, 2019·Organic & Biomolecular Chemistry·Sem Raj TamangMichael Findlater
Jan 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Mariana Luna BarrosPhilip Mountford
Jan 30, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sven KrieckMatthias Westerhausen
Jan 23, 2019·Angewandte Chemie·Heiko BauerSjoerd Harder
Feb 21, 2019·Chemical Communications : Chem Comm·Alberto RamosDaniel García-Vivó
Mar 9, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexa CaiseSimon Aldridge
Apr 4, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Erwann le CozYann Sarazin
Apr 13, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Dafydd D L JonesCameron Jones

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