All-thiolate-stabilized Ag42 nanocluster with a tetrahedral kernel and its transformation to an Ag61 nanocluster with a bi-tetrahedral kernel

Chemical Communications : Chem Comm
Tao ChenManzhou Zhu

Abstract

A new silver nanocluster, formulated as Ag42(SBut)24, was prepared by a NaSbF6-mediated two-phase ligand exchange method. The total structure adopts a quasi-tetrahedral symmetry with a three-layered tetrahedral (Td) Ag10 kernel. Furthermore, with the ligand-etching method, Ag42(SBut)24 can be transformed into Ag61(SC6H11)40Cl, whose kernel structure corresponds to a face-fused bi-tetrahedral Ag14.

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Citations

Jul 13, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiaohang WuManzhou Zhu
Sep 7, 2021·Nanoscale Horizons : the Home for Rapid Reports of Exceptional Significance in Nanoscience and Nanotechnolgy·Tao ChenManzhou Zhu
Oct 6, 2021·Journal of the American Chemical Society·Feng HuQuan-Ming Wang

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Methods Mentioned

BETA
nuclear magnetic resonance
X-ray

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