Aluminum hydroxide colloid facilitated transport of 2,2',4,4'-tetrabromodiphenyl ether (BDE-47) in porous media

Chemosphere
Wenkai QiuYao Du

Abstract

In this study, aluminum hydroxide colloids, which widely exist in soils, were selected to investigate their effect on the infiltration of an abundant congener of PBDEs (BDE-47) to groundwater. The batch and column experiments were conducted to study the co-migration of aluminum hydroxide colloid and BDE-47 in two sand media with particle sizes of 2-4.75 and 0.15 mm. The results indicated that the colloid significantly increased the transport of BDE-47 to 24.32% and 65.84% in the vadose zone of coarse and fine sand columns, respectively. The adsorption and blocking effect were found to be the two main functions during the co-migration of aluminum hydroxide colloids with BDE-47. Specifically, BDE-47 that adsorbed on colloids moved faster in the coarse porous media, and the breakthrough peak of BDE-47 appeared early in the media at an approximate pore volume of 0.15. In comparison, colloids that adsorbed onto the fine porous media formed a layer that blocked the adsorption of BDE-47 onto the fine porous media. This weakened the protection capacity of the vadose zone and led to a greater than 80% amount of BDE-47 breakthrough to the vadose zone.

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