Ambipolar, high performance, acene-based organic thin film transistors

Journal of the American Chemical Society
Ming L TangZhenan Bao

Abstract

We present a high performance, ambipolar organic field-effect transistor composed of a single material. Ambipolar molecules are rare, and they can enable low-power complementary-like circuits. This low band gap, asymmetric linear acene contains electron-withdrawing fluorine atoms, which lower the molecular orbital energies, allowing the injection of electrons. While hole and electron mobilities of up to 0.071 and 0.37 cm2/V.s, respectively, are reported on devices measured in nitrogen, hole mobilities of up to 0.12 cm2/V.s were found in ambient, with electron transport quenched. These devices were fabricated on octadecyltrimethoxysilane-treated surfaces at a substrate temperature of 60 degrees C.

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Citations

May 25, 2013·ACS Applied Materials & Interfaces·Jin Kuen ParkJung Hwa Seo
Sep 14, 2013·ACS Applied Materials & Interfaces·Masashi MamadaShizuo Tokito
Apr 25, 2013·Accounts of Chemical Research·Motonori WatanabeTahsin J Chow
Apr 28, 2011·Inorganic Chemistry·Sreeram CingarapuKenneth J Klabunde
Jun 17, 2011·Inorganic Chemistry·Stefan Durben, Thomas Baumgartner
Sep 2, 2010·Journal of the American Chemical Society·Chun-Yang HeXingang Zhang
Oct 16, 2012·Journal of the American Chemical Society·Long ChenKlaus Müllen
Apr 6, 2013·Journal of the American Chemical Society·Jianguo MeiZhenan Bao
Feb 12, 2009·Journal of the American Chemical Society·Yiqun ZhangMinghua Liu
Feb 27, 2009·Journal of the American Chemical Society·Ming Lee TangZhenan Bao
Jun 13, 2009·Journal of the American Chemical Society·Yutaka ItoZhenan Bao
May 17, 2011·The Journal of Organic Chemistry·Takakazu KimotoKenji Kobayashi
Nov 7, 2013·The Journal of Organic Chemistry·Zheng ZhaoDaoben Zhu
Dec 1, 2011·Organic Letters·Puran K De, Douglas C Neckers
Apr 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Claudio GandolfiMartin Albrecht
May 16, 2013·Physical Chemistry Chemical Physics : PCCP·Monika Stolar, Thomas Baumgartner
Feb 20, 2016·The Journal of Organic Chemistry·Asik HossianRanjan Jana
Mar 31, 2016·The Journal of Physical Chemistry. a·Jian-Xun FanAi-Min Ren
Mar 24, 2017·The Journal of Physical Chemistry. B·Nikhil Aggarwal, Archita Patnaik
Jul 6, 2014·Physical Chemistry Chemical Physics : PCCP·Ke ZhouWenping Hu
Jan 9, 2016·Physical Chemistry Chemical Physics : PCCP·Guankui LongQichun Zhang
Nov 1, 2016·Physical Chemistry Chemical Physics : PCCP·Xia LengYuchen Ma
Aug 18, 2010·Advanced Materials·John E AnthonyXiaowei Zhan

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