Aminoalkoxo-supported heteroleptic hexanuclear gallium(III) wheel as a synthon for group 13 heterometallics: a rare sol-gel precursor for mixed Al-Ga oxide as support for gold catalysts

Dalton Transactions : an International Journal of Inorganic Chemistry
Shashank MishraViolaine Mendez

Abstract

A new heteroleptic gallium(III) complex, Ga(6)Cl(6)(mdea)(6) (1 x 2 CHCl(3)) (mdeaH(2) = N-methyl diethanolamine) was prepared in good yield by a chloro-aminoalkoxo exchange reaction and used as a synthon for the synthesis of a novel group 13 heterometallic derivative, Ga(2)Al(4)(O)(2)(mdea)(2)(OPr(i))(10) (2 x 2 CHCl(3)), the latter acting as a facile single source precursor for the sol-gel preparation of the mixed Al-Ga oxide as a high surface area support for gold catalysts.

References

Oct 10, 2002·Journal of the American Chemical Society·Shashank Sharma, Mahendra K Sunkara
Apr 14, 2004·Chemistry : a European Journal·Rolf W SaalfrankFrank W Heinemann
Oct 13, 2004·Inorganic Chemistry·Evan M RumbergerDavid N Hendrickson
Oct 29, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Siama BasharatDerek A Tocher
Jan 19, 2006·Journal of the American Chemical Society·Massimiliano ComottiFerdi Schüth
Jul 20, 2006·Journal of the American Chemical Society·Chang Hoon LeeKwangyeol Lee
Dec 21, 2006·Chemical Communications : Chem Comm·Pascal LignierValérie Caps
Jan 25, 2008·Chemical Society Reviews·Shashank MishraLiliane G Hubert-Pfalzgraf
Jan 21, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander WillnerNorbert W Mitzel
Mar 26, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Shashank MishraMarc Rolland
Jul 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Violaine MendezValérie Caps

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Citations

Jul 18, 2015·Chemical Reviews·Shashank Mishra, Stéphane Daniele
Nov 14, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Tatiana N SevastianovaAlexey Y Timoshkin
Mar 15, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Shashank MishraStéphane Daniele
Jun 27, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Sweta GahlotShashank Mishra
May 20, 2020·Chemistry : a European Journal·Shashank Mishra, Stéphane Daniele
Dec 3, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Shashank MishraMarie-France Joubert
May 8, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Shashank MishraChristophe Dujardin
Jan 29, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Antonio de Brito Santiago NetoShashank Mishra
Jul 25, 2019·Inorganic Chemistry·Kristian L MearsClaire J Carmalt

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