Aminopiperidine based complexes for lactide polymerisation

Dalton Transactions : an International Journal of Inorganic Chemistry
Paul McKeownMatthew D Jones

Abstract

Herein we report the synthesis and characterisation of a series of salalen and salan ligands derived from 2-(aminomethyl)piperidine. Depending on the choice of starting salicylaldehyde, a bicyclic salan type ligand (1-3H2) or imino salalen type ligand (4-6H, 7-9H2) were prepared. The ligands were successfully complexed to group 4 metals and aluminium; with hafnium and zirconium octahedral complexes, M(1-3)2, were realised; whilst with aluminium tetrahedral and trigonal bipyramidal complexes, Al(1-9)Mex (x = 1,2), were isolated. The complexes have been characterised in solution via(1)H and (13)C{(1)H} NMR spectroscopy and in the solid state by X-ray crystallography. The group 4 complexes were observed to have a fac-fac arrangement of ligands and there were two isomers present when 3H2 was ligated. The imino aluminium complexes Al(7-9)Me were isolated as a mixture of diastereoisomers. The resultant complexes were trialed in the ring opening polymerisation of rac-lactide with both heterotactic and isotactic PLA being demonstrated. Tacticity was found to be dependent on the nature of the ligand and metal used; the M(1-3)2 complexes were generally found to have a heterotactic preference (Pr = 0.67-0.76) and the aluminium polymerisat...Continue Reading

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Citations

Mar 31, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul McKeownMatthew D Jones
Aug 5, 2016·Chemical Communications : Chem Comm·Paul McKeownMatthew D Jones
Oct 22, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jean-Marie E P ColsRuaraidh D McIntosh
Aug 12, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Sarah M KirkMatthew D Jones
Sep 14, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Oliver J DriscollMatthew D Jones

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